Sensitive luminescence mechanochromism and unique luminescence thermochromism tuned by bending the P–O–P skeleton in the diphosphonium/iodocuprate(<scp>i</scp>) hybrid
Zhen-Cong Yang, Kaiyue Song, Pan‐Ke Zhou, Lu-Lu Zong, Hao‐Hong Li, Zhi‐Rong Chen, Rong Jiang
Abstract
The unique luminescence mechano/thermochromism of a diphosphonium/iodocuprate( i ) hybrid is led by the mechanically induced adjustments in cuprophilic interactions and bent P–O–P backbone upon heating.
Topics & Concepts
ThermochromismLuminescenceMaterials scienceBendingOptoelectronicsChemistryComposite materialOrganic chemistryLuminescence and Fluorescent MaterialsCrystallography and molecular interactionsMolecular Sensors and Ion Detection