Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: syntheses and behavior as precursors to PSnP pincer palladium(<scp>ii</scp>), palladium(0) and gold(<scp>i</scp>) complexes
Javier A. Cabeza, Israel Fernández, Pablo García‐Álvarez, Rubén García-Soriano, Carlos J. Laglera‐Gándara, Rubén Toral
Abstract
Metal complexes containing PSnP pincer stannyl and stannylene ligands have been prepared from new pyrrole- and dipyrromethane-based PSnP stannylenes.
Topics & Concepts
Pincer movementPalladiumChemistryLigand (biochemistry)Medicinal chemistryPincer ligandPyrroleTransition metalMetalPolymer chemistryCombinatorial chemistryCatalysisOrganic chemistryBiochemistryReceptorOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and Organometallics