Iridium-promoted deoxyglycoside synthesis: stereoselectivity and mechanistic insight
Kumar Bhaskar Pal, Aoxin Guo, Mrinmoy Das, Jiande Lee, Gábor Báti, Benjamin Rui Peng Yip, Teck‐Peng Loh, Xue‐Wei Liu
Abstract
-addition manner. This protocol exhibits good functional group tolerance and is exemplified with the preparation of a library of oligosaccharides in moderate to high yields and with excellent stereoselectivities.
Topics & Concepts
StereoselectivityIridiumGlycosylationChemistrySubstrate (aquarium)Scope (computer science)SelectivityCombinatorial chemistryCatalysisOrganic chemistryBiochemistryComputer scienceBiologyEcologyProgramming languageCarbohydrate Chemistry and SynthesisChemical Synthesis and AnalysisSynthesis and Catalytic Reactions