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Finite Element Modeling of the Combined Faradaic and Electrostatic Contributions to the Voltammetric Response of Monolayer Redox Films

Katherine J. Levey, Martin A. Edwards, Henry S. White, Julie V. Macpherson

2022Analytical Chemistry16 citationsDOIOpen Access PDF

Abstract

determination at all scan rates. The electric potential and charge distributions across an electrochemically inactive monolayer and electrolyte solution are also simulated as a function of applied potential and are found to agree with the Gouy-Chapman-Stern theory.

Topics & Concepts

ChemistryElectrolyteMonolayerRedoxElectric potentialOhmic contactFinite element methodElectron transferDistortion (music)Nernst equationAnalytical Chemistry (journal)Molecular physicsChemical physicsThermodynamicsElectrodeInorganic chemistryPhysical chemistryMaterials sciencePhysicsVoltageQuantum mechanicsAmplifierChromatographyCMOSOptoelectronicsBiochemistryMolecular Junctions and NanostructuresElectrochemical Analysis and ApplicationsConducting polymers and applications
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