Design Principle of Insulating Surface Protective Layers for Metallic Zn Anodes: A Case Study of ZrO<sub>2</sub>
Binbin Wei, Jiaxian Zheng, Abhishek Abhishek, Xin Liu, Jingang Wu, Zhengbing Qi, Zhuo Hou, Rui Wang, Jidong Ma, Appala Naidu Gandi, Zhoucheng Wang, Hanfeng Liang
Abstract
Abstract Aqueous Zn batteries, which use metallic Zn as anodes, have gained significant attention due to their affordability and high safety standards. However, these Zn anodes are plagued by issues such as Zn dendritic growth and side reactions, including corrosion and hydrogen evolution. One straightforward yet effective approach to mitigate these issues is to apply protective coatings to the Zn anodes to enhance their reversibility. It is generally believed that these protective layers should have a high affinity for Zn. Contrarily, this study proposes that non‐conductive coatings should form a strong binding with H + ions while maintaining a weaker interaction with Zn 2+ ions, thereby ensuring a higher selectivity for H + over Zn 2+ . This concept is illustrated using zirconium dioxide (ZrO 2 ), an ionic conductor that meets these criteria and effectively curbs side reactions and dendritic growth of Zn. Remarkably, Zn anodes coated with ZrO 2 layer demonstrate a lifespan exceeding 6000 h at 1 mA cm −2 and 1 mAh cm −2 , significantly outperforming uncoated ones, which last <200 h. This discovery introduces a novel design principle for insulating surface coatings, potentially applicable not only for Zn but also for other metal anodes.