Photolytic amino etherification reactions of aryl diazoacetates with N-heterocycles and a stoichiometric amount of dioxane/tetrahydropyran in aqueous medium: synthesis of 1,4-dioxepane/1,4,7-dioxazonan-6-one systems
Debajit Maiti, Ranajit Das, Subhabrata Sen
Abstract
Herein we have reported a blue LED mediated reaction of aryl diazoacetate with a stoichiometric amount of 1,4-dioxane/tetrahydropyran and various heterocycles like indoles, pyrrole, phthalimide, succinimide, thiazolidinedione and hydantoin in water.
Topics & Concepts
TetrahydropyranChemistryStoichiometryArylSuccinimidePyrroleAqueous solutionPhthalimideOrganic chemistryAqueous mediumAlkylRing (chemistry)Cyclopropane Reaction MechanismsChemical Reactions and MechanismsSynthesis and Catalytic Reactions