A photochemical halogen-atom-transfer pathway for the carboxylation of alkenes with CO<sub>2</sub>
Senmao Zhai, Rong Wang, Quanfeng Dong, Jiajia Cheng, Meifang Zheng, Xinchen Wang
Abstract
A synergic photocatalysis/halogen-atom-transfer strategy offers a mild, sustainable, and practical method for the carboalkylation of electron-deficient alkenes using CO 2 as the C1 source and commercially available alkyl iodides as building blocks.
Topics & Concepts
ChemistryHalogenPhotochemistryCarboxylationElectron transferPhotocatalysisAtom (system on chip)AlkylOrganic chemistryCatalysisComputer scienceEmbedded systemCarbon dioxide utilization in catalysisFluorine in Organic ChemistryCO2 Reduction Techniques and Catalysts