Mixed noble metal–oxo clusters: platinum(<scp>iv</scp>)–gold(<scp>iii</scp>) oxoanion [Pt<sup>IV</sup><sub>2</sub>Au<sup>III</sup><sub>3</sub>O<sub>6</sub>((CH<sub>3</sub>)<sub>2</sub>AsO<sub>2</sub>)<sub>6</sub>]<sup>−</sup>
Jiayao Zhang, Saurav Bhattacharya, Anja B. Müller, Levente Kiss, Cristian Silvestru, Nikolai Kuhnert, Ulrich Kortz
Abstract
Pt) NMR, indicating that polyanion 1 is stable in solution, which was confirmed by ESI-MS studies. The sodium salt of 1 undergoes a clean single-crystal-to-single-crystal (SCSC) structural transformation upon rehydration and dehydration.
Topics & Concepts
ChemistryPlatinumSingle crystalSodiumAqueous solutionCrystallographySalt (chemistry)MetalPotassiumYield (engineering)Inorganic chemistryNuclear chemistryCatalysisPhysical chemistryOrganic chemistryMaterials scienceMetallurgyPolyoxometalates: Synthesis and ApplicationsMetal complexes synthesis and propertiesNanocluster Synthesis and Applications