Nitrogen-Containing Perylene Diimides: Molecular Design, Robust Aggregated Structures, and Advances in n-Type Organic Semiconductors
Shohei Kumagai, Hiroyuki Ishii, Go Watanabe, Craig P. Yu, Shun Watanabe, Jun Takeya, Toshihiro Okamoto
Abstract
-based material, demonstrating solution-processable thin-film single crystals, fewer anisotropic transfer integrals, and an effective suppression of molecular motions, leading to band-like electron-transport properties and stress-durable n-channel OTFT performances, in conjunction with the support of computational calculations. Insights into more fundamental points of view have been found by side-chain derivatization and OTFT studies on polycrystalline and single-crystal films. We hope that this Account provides readers with new strategies for designing high-performance OSCs by two-dimensional control of the aggregated structures.
Topics & Concepts
Electron mobilitySemiconductorOrganic semiconductorDiimideTransistorNanotechnologyMaterials scienceField-effect transistorOrganic electronicsChemistryPeryleneOptoelectronicsMoleculePhysicsOrganic chemistryVoltageQuantum mechanicsOrganic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesDiamond and Carbon-based Materials Research