Effects of structural variations on π-dimer formation: long-distance multicenter bonding of cation-radicals of tetrathiafulvalene analogues
John T. Brown, Matthias Zeller, Sergiy V. Rosokha
Abstract
˙ cation-radicals was related to a decrease of the electrostatic repulsion between cationic counter-parts and an increase of dispersion components in these associations.
Topics & Concepts
TetrathiafulvaleneRadicalDimerChemistryCrystallographyMoleculeOrganic chemistryOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallographyCrystallography and molecular interactions