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Convergent paired electrosynthesis of dimethyl carbonate from carbon dioxide enabled by designing the superstructure of axial oxygen coordinated nickel single-atom catalysts

Xiaofang Li, Shu‐Guo Han, Weiming Wu, Kexin Zhang, Bo Chen, Shenghua Zhou, Dong-Dong Ma, Wenbo Wei, Xin‐Tao Wu, Ruqiang Zou, Qi‐Long Zhu

2022Energy & Environmental Science142 citationsDOI

Abstract

A dual-channel superstructured Ni single-atom catalyst with a unique axial oxygen coordination configuration was controllably constructed and affords a preeminent performance for convergent paired electrosynthesis of dimethyl carbonate from CO 2 .

Topics & Concepts

ElectrosynthesisNickelCarbonateCatalysisSuperstructureDimethyl carbonateCarbon dioxideOxygen evolutionOxygen atomOxygenMaterials scienceAtom (system on chip)ChemistryChemical engineeringNanotechnologyElectrochemistryPhysical chemistryElectrodeMetallurgyOrganic chemistryPhysicsMoleculeThermodynamicsComputer scienceEmbedded systemEngineeringCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisAdvanced battery technologies research
Convergent paired electrosynthesis of dimethyl carbonate from carbon dioxide enabled by designing the superstructure of axial oxygen coordinated nickel single-atom catalysts | Litcius