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Metal‐Organic Frameworks and Metal‐Organic Cages – A Perspective

Ben S. Pilgrim, Neil R. Champness

2020ChemPlusChem143 citationsDOIOpen Access PDF

Abstract

The fields of metal-organic cages (MOCs) and metal-organic frameworks (MOFs) are both highly topical and continue to develop at a rapid pace. Despite clear synergies between the two fields, overlap is rarely observed. This article discusses the peculiarities and similarities of MOCs and MOFs in terms of synthetic strategies and approaches to system characterisation. The stability of both classes of material is compared, particularly in relation to their applications in guest storage and catalysis. Lastly, suggestions are made for opportunities for each field to learn and develop in partnership with the other.

Topics & Concepts

Metal-organic frameworkGeneral partnershipNanotechnologyPaceMaterials scienceBiochemical engineeringChemistryEngineeringOrganic chemistryBusinessPhysicsFinanceAstronomyAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMagnetism in coordination complexes