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Crystal engineering with pyrazolyl-thiazole derivatives: structure-directing role of π-stacking and σ-hole interactions

Muhammad Naeem Ahmed, Murtaza Madni, Shaista Anjum, Saiqa Andleeb, Shahid Hameed, Abdul Majeed Khan, Muhammad Ashfaq, Muhammad Nawaz Tahir, Diego M. Gil, Antonio Frontera

2021CrystEngComm30 citationsDOIOpen Access PDF

Abstract

The structure-directing role of a variety of noncovalent interactions in the solid state of pyrazolyl-thiazole derivatives has been analyzed energetically using DFT calculations and by means of Hirshfeld surface analysis.

Topics & Concepts

ThiazoleStackingCrystal structureNon-covalent interactionsCrystallographyChemistrySolid-stateCrystal (programming language)Computational chemistryMaterials scienceStereochemistryMoleculeOrganic chemistryPhysical chemistryHydrogen bondComputer scienceProgramming languageCrystallography and molecular interactionsCrystal structures of chemical compoundsNonlinear Optical Materials Research