Lithium Storage Performance Boosted via Delocalizing Charge in Zn<i><sub>x</sub></i>Co<sub>1−</sub><i><sub>x</sub></i>PS<sub>3</sub>/CoS<sub>2</sub> of 2D/3D Heterostructure
Hou‐Yang Zhong, Xian Lu, Yu Zhong, Yi Zhao, Xin‐Ming Liu, Danhong Cheng, Xiao‐Ying Huang, Ke‐Zhao Du, Xiaohui Wu
Abstract
Abstract A promising anode material consisting of bimetallic thiophosphate Zn x Co 1− x PS 3 and CoS 2 with 2D/3D heterostructure is designed and prepared by an effective chemical transformation. Density functional theory calculations illustrate that the Zn 2+ can effectively modulate the electrical ordering of Zn x Co 1− x PS 3 on the nanoscale: the reduced charge distribution emerging around the Zn ions can enhance the local built‐in electric field, which will accelerate the ions migration rate by Coulomb forces and provide tempting opportunities for manipulating Li + storage behavior. Moreover, the merits of the large planar size enable Zn x Co 1– x PS 3 to provide abundant anchoring sites for metallic CoS 2 nanocubes, generating a 2D/3D heterostructure with a strong electric field. The resultant Zn x Co 1− x PS 3 /CoS 2 can offer the combined advantages of bimetallic alloying and heterostructure in lithium storage applications, leading to outstanding performance as an anode material for lithium‐ion batteries. Consequently, a high capacity of 794 mA h g −1 can be retained after 100 cycles at 0.2 A g −1 . Even at 3.0 A g −1 , a satisfactory capacity of 465 mA h g −1 can be delivered. The appealing alloying‐heterostructure and electrochemical performance of this bimetallic thiophosphate demonstrate its great promise for applications in practical rechargeable batteries.