Enhancing the selectivity of prolinamide organocatalysts using the mechanical bond in [2]rotaxanes
María Calles García, Julio Puigcerver, Diego A. Alonso, Mateo Alajarı́n, Alberto Martínez‐Cuezva, José Berná
Abstract
-hexylthymine as a cofactor to form supramolecular catalysts displaying a divergent catalytic behaviour. The presence or absence of the cofactor controls the chemoselectivity in competitive reactions.
Topics & Concepts
SelectivityChemistryOrganic chemistryCatalysisAsymmetric Synthesis and CatalysisCrystallography and molecular interactionsSupramolecular Chemistry and Complexes