Visible-light-mediated tandem phosphorylation/cyclization for the synthesis of phosphorylated oxindoles
Liu‐Liang Mao, An‐Xi Zhou, Xianhong Zhu, Lixia Quan, Fa‐Yun Chen, Jie‐Ping Wan, Yinlong Lai
Abstract
-arylacrylamides with H-phosphine oxides has been developed for the synthesis of phosphorylated oxindoles. This efficient and facile process was useful for the construction of a C-P bond and triggered the formation of a C-C bond with good compatibility with functional groups undermild reaction conditions.
Topics & Concepts
TandemPhosphorylationChemistryCompatibility (geochemistry)PhosphineVisible spectrumPhosphorylation cascadeCombinatorial chemistryBiochemistryCatalysisProtein phosphorylationMaterials scienceProtein kinase AOptoelectronicsComposite materialSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions