Topological polymorphism and temperature-driven topotactic transitions of metal–organic coordination polymers
Vadim A. Dubskikh, Anna A. Lysova, Denis G. Samsonenko⧫, Danil N. Dybtsev, Vladimir P. Fedin
Abstract
A facile crystal-to-crystal solid-state phase transition between a low-temperature phase and a high temperature phase changes the MOF topology and involves a significant rearrangement of bulky organic ligands.
Topics & Concepts
Polymorphism (computer science)PolymerCoordination polymerMetalTopology (electrical circuits)Materials scienceChemistryNanotechnologyOrganic chemistryMetallurgyMathematicsGenotypeGeneCombinatoricsBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsX-ray Diffraction in Crystallography