Ligand electronic fine-tuning and its repercussion on the photocatalytic activity and mechanistic pathways of the copper-photocatalysed aza-Henry reaction
Chenfei Li, Robert Dickson, Nils Rockstroh, Jabor Rabeah, David B. Cordes, Alexandra M. Z. Slawin, Paul Hünemörder, Anke Spannenberg, Michæl Bühl, Esteban Mejía, Eli Zysman‐Colman, Paul C. J. Kamer
Abstract
Subtle electronic ligand effects have a strong impact on the mechanistic pathway of a photocatalytic coupling reaction.
Topics & Concepts
PhotocatalysisLigand (biochemistry)CatalysisCopperChemistryCoupling (piping)PhotochemistryCombinatorial chemistryMaterials scienceOrganic chemistryReceptorBiochemistryMetallurgyRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsCO2 Reduction Techniques and Catalysts