High efficient removal of lead(II) and cadmium(II) ions from multi-component aqueous solutions using polyacrylic acid acrylonitrile talc nanocomposite
M. R. Abass, Wafaa Mohamed El-Kenany, E.H. EL-Masry
Abstract
Abstract This study is interested in the removal of Pb(II), Cd(II), Co(II), Zn(II), and Sr(II) onto polyacrylic acid acrylonitrile talc P(AA-AN)-talc nanocomposite. P(AA-AN)-talc was fabricated using γ-irradiation-initiated polymerization at 50 kGy. Different analytical tools were used to investigate the functional groups, morphology, particle size, and structure of this composite. The ability of P(AA-AN)-talc to capture (Pb 2+ , Cd 2+ , Co 2+ , Zn 2+ , and Sr 2+ ) as multi-component aqueous solutions was performed by a batch method. Saturation capacity and the effect of (agitating time, pH, initial metal concentrations, and temperature) were investigated. The distribution coefficients at different pHs have order: Pb 2+ > Cd 2+ > Co 2+ > Zn 2+ > Sr 2+ . The saturation capacity decreases by increasing heating temperatures. Reaction kinetic obeys the pseudo-second-order model. Sorption isotherms are more relevant to a Langmuir isotherm, and the monolayer sorption capacity is closed to saturation capacity. Thermodynamic parameters (∆G˚, ∆H˚, and ∆S˚) were endothermic and spontaneous. P(AA-AN)-talc is used for loading and recovery of studied cations in the column system. The study confirms that P(AA-AN)-talc is a promised composite for the sorption of the studied ions from aqueous solutions and should be considered as potential material for decontaminating these ions. Graphical abstract