Detecting Fe(II) Spin-Crossover by Modulation of Appended Eu(III) Luminescence in a Single Molecule
Neel Deorukhkar, Lotti Egger, Laure Guénée, Céline Besnard, Claude Piguet
Abstract
Multifunctionality in spin-crossover (SCO) devices is limited to macroscopic or nanoscopic materials because of the need for long-range effects for inducing favorable cooperativity, efficient energy migration processes, and detectable magnetization transfer. The difficult reproducibility, control, and rational design of doped materials offer some place to SCO processes, modulating the optical properties of neighboring luminescent probes in single molecules. We report here on the combination of a [FeN 6 ] chromophore, the SCO temperature and absorption spectra of which have been tuned to induce unprecedented room-temperature modulation of Eu(III)-based line-like luminescence in the molecular triple-helical [EuFe( L2 ) 3 ] 5+ complex in solution.