Switchable <i>In Situ</i> SO<sub>2</sub> Capture and CF<sub>3</sub> Migration of Enol Triflates with Peroxyl Compounds under Iron Catalysis
Qi-Chao Shan, Shuai Liu, Yuncheng Shen, Mingming Ma, Xin‐Hua Duan, Pin Gao, Li‐Na Guo
Abstract
migration of enol triflates with peroxyl compounds under iron catalysis are presented. By regulating the structure of peroxides, a variety of keto-functionalized dialkyl sulfones and α-trifluoromethyl ketones were selectively synthesized in good yields under mild conditions.
Topics & Concepts
ChemistryEnolCatalysisIn situTrifluoromethylCombinatorial chemistryOrganic chemistryPhotochemistryAlkylSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsRadical Photochemical Reactions