Experimental and theoretical study of Criegee intermediate (CH<sub>2</sub>OO) reactions with <i>n</i>-butyraldehyde and isobutyraldehyde: kinetics, implications and atmospheric fate
Amit Kumar Debnath, B. Rajakumar
Abstract
The reactions of the simplest Criegee intermediate (CH 2 OO) with n -butyraldehyde ( n BD) and isobutyraldehyde (iBD) were studied at 253–318 K and (50 ± 2) torr, using Cavity Ring-down spectroscopy (CRDS).
Topics & Concepts
IsobutyraldehydeButyraldehydeChemistryKineticsRing (chemistry)Cavity ring-down spectroscopySpectroscopyComputational chemistryTorrPhotochemistryPhysical chemistryCatalysisOrganic chemistryThermodynamicsPhysicsQuantum mechanicsAtmospheric chemistry and aerosolsSpectroscopy and Laser ApplicationsAtmospheric Ozone and Climate