Formation and properties of spindle-shaped aragonite mesocrystals from Mg-bearing solutions

Abstract

ions in the assembly of aragonite spindles. Whereas the mesoscale-ordered arrangement of nanocrystals implies a particle-mediated assembly, the observed differences in particle size and composition between the amorphous precursor and the crystalline end-product suggest that the crystallization includes at least partial dissolution and re-precipitation. These findings provide insight into the formation of aragonite and could contribute to the understanding of important aspects of the formation of mesocrystals and hierarchically structured biogenic minerals.

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