Facile C–H bond activation on a transient gallium imide
Aishabibi Kassymbek, Denis M. Spasyuk, Anton Dmitrienko, Melanie Pilkington, Georgii I. Nikonov
Abstract
C-H bonds of different substrates, affording gallium amides. Pyridine, cyclohexanone, ethyl acetate, DMSO, and triethylphosphine oxide were activated in this process producing corresponding gallium amides. All new compounds were characterised by multinuclear NMR and X-ray diffraction.
Topics & Concepts
ImideGalliumCyclohexanoneChemistryAzideMorpholinePyridineMedicinal chemistryPolymer chemistryOrganic chemistryCatalysisCoordination Chemistry and OrganometallicsOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compounds