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Reversible “on–off” conversion and ultra-high temperature sensitivity of a zero-dimensional lead-free Cs<sub>2</sub>InBr<sub>5</sub>(H<sub>2</sub>O):Sb<sup>3+</sup> perovskite

Maohao Yang, Wanyin Ge, Kenshi Matsumoto, Masaki Saruyama, Ryota Sato, Haruka Takekuma, Ryo Takahata, Toshiharu Teranishi

2024Inorganic Chemistry Frontiers10 citationsDOIOpen Access PDF

Abstract

We observed that the water molecule in the Cs 2 InBr 5 (H 2 O):Sb 3+ molecular structure acts as a switch, facilitating an “on–off–on” cycle that can be repeated multiple times, overcoming the limitations of materials that exhibit singular responses.

Topics & Concepts

Materials scienceSensitivity (control systems)Analytical Chemistry (journal)RadiochemistryChemistryEnvironmental chemistryElectronic engineeringEngineeringPerovskite Materials and ApplicationsOptical properties and cooling technologies in crystalline materialsSolid-state spectroscopy and crystallography
Reversible “on–off” conversion and ultra-high temperature sensitivity of a zero-dimensional lead-free Cs<sub>2</sub>InBr<sub>5</sub>(H<sub>2</sub>O):Sb<sup>3+</sup> perovskite | Litcius