Crystal facet effects of platinum single-atom catalysts in hydrolytic dehydrogenation of ammonia borane
Qingdi Sun, Xuyu Wang, Hao Wang, Hao Zhang, Qian He, Ying Zhang, Yujie Cheng, Xingcong Zhang, Shaolin Shi, Leiming Tao, Xiaohui He, Hongbing Ji
Abstract
More electron depletion of the Pt center of the Pt 1 /Co 3 O 4 -c surface facilitates overall electron transfer from the B atom to the ammonia borane (AB) molecule, which ensures the highest activity among Pt 1 /Co 3 O 4 -x in the hydrolytic dehydrogenation of AB reaction.
Topics & Concepts
Ammonia boraneDehydrogenationCatalysisChemistryPlatinumCrystallographyAmmoniaBoraneAtom (system on chip)MoleculeSingle crystalHydrolysisFacet (psychology)Inorganic chemistryPhotochemistryOrganic chemistrySocial psychologyPersonalityPsychologyBig Five personality traitsEmbedded systemComputer scienceHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionMetal-Organic Frameworks: Synthesis and Applications