Metal–Organic Framework-Derived ZnO, N Dually Doped Nanocages as an Efficient Host for Stable Li Metal Anodes
Zilong Zhuang, Fuming Zhang, Dayakar Gandla, Vijaykumar V. Jadhav, Zhaoxi Liu, Liangsheng Hu, Fushen Lu, Daniel Q. Tan
Abstract
The drastic volume expansion and dendrite growth of lithium metal anodes give rise to poor electrochemical reversibility. Herein, ZnO, N dually doped nanocages (c-ZNCC) were synthesized as the host for lithium metal anodes using the zeolitic imidazolate framework-8 (ZIF-8). The synthesis is based on a two-step core@shell evolution mechanism, which could guide lithium deposition rapidly and offer a fast lithium-ion diffusion during the cycling process. Benefiting from the unique design, the as-obtained c-ZNCC can render a record short lithium infusion as low as 1.5 s, a stable lithium stripping/plating capability as long as 3000 h, and a voltage hysteresis of 95 mV when cycling at 10 mA cm –2 to 10 mA h cm –2 . A low Tafel slope of 3.45 mA cm –2 demonstrates the efficient charge transfer of c-ZNCC-Li, and the galvanostatic intermittent titration technique measurement shows high diffusion coefficient of c-ZNCC-Li during the charging process. In addition, the LNMO||c-ZNCC-Li cell exhibits a capacity retention as high as 93.7% at 1 C after 200 cycles. This work creates a new design for deriving nanocages with dual lithiophilic spots using a metal–organic framework and carbon cloth for favorable Li metal anodes.