A Promoter‐free Protocol for the Synthesis of Selenophosphates and Thiophosphates <i>via</i> a Spontaneous Process at Room Temperature
Bin Yang, Xinyue Zhang, Hui‐Qi Yue, Wen‐Zuo Li, Ming Li, Lu Lu, Zi‐Qian Wu, Ji Li, Kai Sun, Shang‐Dong Yang
Abstract
Abstract A promoter‐free chalcogenophosphorylation reaction between diverse P(O)−H reagents and chalcogenosulfonates has been developed. In the absence of metal or any other additives, these transformations proceed through a spontaneous process at room temperature, which provide a convenient and compatible approach to a broad range of selenophosphates and thiophosphates. magnified image
Topics & Concepts
ChemistryReagentCombinatorial chemistryAtmospheric temperature rangeProcess (computing)MetalNanotechnologyOrganic chemistryThermodynamicsOperating systemMaterials scienceComputer sciencePhysicsSulfur-Based Synthesis TechniquesOrganophosphorus compounds synthesisSynthesis and Reactivity of Sulfur-Containing Compounds