Dynamic environment at the <b>Zr</b><sub><b>6</b></sub> oxo cluster surface is key for the catalytic formation of amide bonds
Yujie Zhang, Ismail Y. Kokculer, Francisco de Azambuja, Tatjana N. Parac‐Vogt
Abstract
Catalytic formation of amide bonds by a discrete Zr 6 O 8 cluster reveals a dynamic environment on the cluster surface, providing key molecular insights on its intrinsic reactivity for the design of cluster-based and MOF catalysts.
Topics & Concepts
Cluster (spacecraft)CatalysisAmideReactivity (psychology)ChemistryCharacterization (materials science)Key (lock)StereochemistryMaterials scienceNanotechnologyOrganic chemistryComputer scienceProgramming languageAlternative medicinePathologyMedicineComputer securityMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase MaterialsChemical Synthesis and Analysis