Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes
Jun Zhou, Zhengyu Zhao, Bingyao Jiang, Katsuhiro Yamamoto, Yuji Sumii, Norio Shibata
Abstract
)-H bond, including diarylmethanes, diarylethanes, and monoarylalkanes. Many di- and triarylalkanes with tertiary or quaternary carbon centers can be obtained easily in moderate to high yields. We believe that the developed silylboronate-mediated cross-coupling method is a valuable contribution to C-F and C-H activation chemistry.
Topics & Concepts
ArylChemistryHalideCatalysisSilylationTransition metalCoupling reactionBond cleavageCoupling (piping)MetalCombinatorial chemistryComputational chemistryPhotochemistryCrystallographyOrganic chemistryMaterials scienceAlkylMetallurgyFluorine in Organic ChemistryRadical Photochemical ReactionsSulfur-Based Synthesis Techniques