Hydrous cobalt–iridium oxide two-dimensional nanoframes: insights into activity and stability of bimetallic acidic oxygen evolution electrocatalysts
Yuanfang Ying, Jose Fernando Godínez Salomón, Luis Lartundo‐Rojas, Ashley N Moreno, Robert G. Meyer, Craig A. Damin, Christopher P. Rhodes
Abstract
resulted in lowering of the specific activity and partial dissolution of Ir. In contrast, the durability testing of hydrous Co-Ir oxide nanoframes resulted in the combination of a higher Ir dissolution rate, an increase in the relative contribution of surface iridium hydroxide groups and an increase in specific activity. The understanding of the differences in degradation processes between bimetallic and monometallic catalysts furthers our ability to design high activity and stability acidic OER electrocatalysts.
Topics & Concepts
Bimetallic stripIridiumOxygen evolutionDissolutionCatalysisOxideHydroxideCobaltChemical engineeringCobalt oxideInorganic chemistryMaterials scienceElectrochemistryElectrocatalystChemistryElectrodeMetallurgyPhysical chemistryOrganic chemistryEngineeringElectrocatalysts for Energy ConversionFuel Cells and Related MaterialsAdvanced battery technologies research