Unravelling the role of active-site isolation in reactivity and reaction pathway control for acetylene hydrogenation
Siyang Liu, Yiming Niu, Yongzhao Wang, Junnan Chen, Xueping Quan, Xia Zhang, Bingsen Zhang
Abstract
catalysts with precisely controlled Pd/Cu ratios were prepared and characterized by combining sample averaged and microscopic techniques. The active-site isolation effect on reactivity and reaction pathway control with different extent of Pd ensembles in acetylene hydrogenation is unravelled systematically.
Topics & Concepts
Bimetallic stripAcetyleneReactivity (psychology)CatalysisActive siteChemistryIsolation (microbiology)PhotochemistryCombinatorial chemistryOrganic chemistryBioinformaticsBiologyPathologyMedicineAlternative medicineAsymmetric Hydrogenation and CatalysisCatalytic Processes in Materials ScienceCatalysis for Biomass Conversion