CH<sub>2</sub>OO Criegee intermediate UV absorption cross-sections and kinetics of CH<sub>2</sub>OO + CH<sub>2</sub>OO and CH<sub>2</sub>OO + I as a function of pressure
Zara S. Mir, Thomas R. Lewis, Lavinia Onel, Mark A. Blitz, Paul W. Seakins, Daniel Stone
Abstract
The UV absorption cross-sections of the Criegee intermediate CH<sub>2</sub>OO, and kinetics of the CH<sub>2</sub>OO self-reaction and the reaction of CH<sub>2</sub>OO with I are reported as a function of pressure at 298 K.
Topics & Concepts
KineticsChemistryFlash photolysisAbsorption (acoustics)Analytical Chemistry (journal)Absorption cross sectionTorrChemical kineticsAbsorption spectroscopyPhotodissociationSpectroscopyReaction rate constantCross section (physics)PhotochemistryMaterials scienceOpticsThermodynamicsOrganic chemistryPhysicsComposite materialQuantum mechanicsSpectroscopy and Laser ApplicationsAtmospheric Ozone and ClimateAtmospheric chemistry and aerosols