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Interplay between structural parameters and reactivity of Zr<sub>6</sub>-based MOFs as artificial proteases

Alexandra Loosen, Francisco de Azambuja, Simon Smolders, Jens Moons, Charlotte Simms, Dirk De Vos, Tatjana N. Parac‐Vogt

2020Chemical Science63 citationsDOIOpen Access PDF

Abstract

term. The reactivity of NU-1000 towards a hen egg white lysozyme protein under physiological pH was also evaluated, and the results pointed to a selective cleavage at only 3 peptide bonds. This showcases the potential of Zr-MOFs to be developed into heterogeneous catalysts for non-enzymatic but selective transformation of biomolecules, which are crucial for many modern applications in biotechnology and proteomics.

Topics & Concepts

Reactivity (psychology)HydrolysisCatalysisProteasesMaterials sciencePeptideChemistryCombinatorial chemistryOrganic chemistryEnzymeBiochemistryPathologyAlternative medicineMedicineMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase MaterialsAdvanced Nanomaterials in Catalysis