Excited-state antiaromaticity relief drives facile photoprotonation of carbons in aminobiphenyls
Josip Draženović, Croix J. Laconsay, Nađa Došlić, Judy I. Wu, Nikola Basarić
Abstract
-isomer, which involves a triplet excited-state. Computations illustrate the important role of excited-state antiaromaticity relief in these photoreactions.
Topics & Concepts
AntiaromaticityExcited stateState (computer science)ChemistryNanotechnologyMaterials sciencePhysicsComputer scienceAtomic physicsOrganic chemistryAromaticityMoleculeAlgorithmPhotochemistry and Electron Transfer StudiesRadical Photochemical ReactionsPhotochromic and Fluorescence Chemistry