Toughening and high-temperature self-lubricating of high-entropy boride ceramics through h-BN
Hao Ying, Qilong Guo, Yinghao Wen, Ziqiu Shi, Zhi Jin, Bowen Yuan, Jingqing Zhang, Jingwei Wu, Hengzhong Fan, Xiufang Wang
Abstract
High-entropy boride ceramics demonstrate outstanding high-temperature stability, positioning them as promising candidates for reliable performance in extreme environments. However, their inherent limitation lies in relatively low fracture toughness, coupled with the unclear elucidation of high-temperature tribological behaviors. To address these challenges, high-entropy (Ti<sub>0.2</sub>Zr<sub>0.2</sub>Hf<sub>0.2</sub>Nb<sub>0.2</sub>Ta<sub>0.2</sub>)B<sub>2</sub> (HEB) ceramics are utlized as the matrix material in the current investigation, while hexagonal boron nitride (h-BN) is introduced as a type of toughening and lubricating phase to develop HEB-hBN composite ceramics. The toughening and high-temperature self-lubrication of the composites are achieved by leveraging the high aspect ratio, lamellar microstructure, and interlayer slip characteristics of h-BN. Results indicate that h-BN enhances the fracture toughness of the composite ceramics by nearly 70%, attributed to the optimization of the crack growth path through its lamellar microstructure and facilitating crack deflection and bridging mechanisms due to its high aspect ratio. Moreover, through interlayer slip effects, h-BN collaborates with B<sub>2</sub>O<sub>3</sub> and metal oxides generated from high-temperature oxidation, forming a gradient tribofilm in conjunction with other synergistic lubrication mechanisms. This synergistic interaction results in a nearly 40% reduction in the friction coefficient of the composite ceramics, accompanied by an approximately 60% decrease in wear rate under high-temperature friction conditions at 1000 °C. Under extreme friction environments ranging from 1000 °C to 1200 °C, the composite ceramic maintains a friction coefficient consistently below 0.30, with the wear rate stably sustained at an order of magnitude of 10<sup>-5</sup> mm<sup>3</sup>/(N·m).