Tuning molecular adsorption in SBA-15-type periodic mesoporous organosilicas by systematic variation of their surface polarity
Hyunjin Moon, Songi Han, Susannah L. Scott
Abstract
-cresol, or furfural when these molecules are dissolved in water. However, stronger solute-surface interactions and favor adsorption as the surface polarity decreases. The trend is reversed for furfural in benzene, where weaker solvent-surface interactions result in higher adsorption on polar surfaces. In DMSO, furfural adsorption is suppressed due to the similar strengths of solute-surface and solvent-surface interactions. Thus, the polarity of the surface relative to the solvent is critical for molecular adsorption. These findings show how adsorption/desorption can be precisely and systematically tuned by appropriate choice of both solvent and surface, and contribute to a predictive strategy for the design of catalytic and separations processes.