A rare 4-connected neb-type 3D chiral polyoxometalate framework based on {KNb<sub>24</sub>O<sub>72</sub>} clusters
Zeng‐Kui Zhu, Li‐Dan Lin, Jing Zhang, Xin‐Xiong Li, Yan‐Qiong Sun, Shou‐Tian Zheng
Abstract
A rare 3D porous chiral polyoxoniobate framework has been constructed from two types of isomeric {Cu(en)<sub>2</sub>KNb<sub>24</sub>O<sub>72</sub>} clusters with a 4-connected neb-type topology. This compound exhibits proton conduction and high water vapor adsorption properties.
Topics & Concepts
PolyoxometalateProtonAdsorptionType (biology)CrystallographyMaterials scienceCluster (spacecraft)ChemistryTopology (electrical circuits)Physical chemistryPhysicsOrganic chemistryCatalysisComputer scienceMathematicsCombinatoricsBiologyEcologyQuantum mechanicsProgramming languagePolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications