Ni-catalyzed regioselective and site-divergent reductive arylalkylations of allylic amines
Huan Meng, Jun-Song Jia, Pengfei Yang, Yulong Li, Qiong Yu, Wei Shu
Abstract
A Ni-catalyzed cross-electrophile regioselective and site-divergent 1,2- and 1,3-arylalkylations of allylic amines has been developed, representing the first controllable migratory difunctionalization of alkenes under reductive conditions.
Topics & Concepts
RegioselectivityAllylic rearrangementCatalysisChemistryCombinatorial chemistryStereochemistryOrganic chemistryCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsAsymmetric Hydrogenation and Catalysis