Polymerization with the Cu(<scp>i</scp>)-catalyzed Doyle–Kirmse reaction of bis(allyl sulfides) and bis(α-diazoesters)
Zihao Fu, Qi Zhou, Yiyang Xiao, Jianbo Wang
Abstract
The Doyle–Kirmse reaction of α-diazoester and allyl sulfide has been developed into a polymerization process for the first time, affording a series of unique sulfur-containing polymers with molecular weights up to 23.7 kDa in good yields.
Topics & Concepts
PolymerizationSulfideChemistryCatalysisSulfurPolymer chemistryPolymerMedicinal chemistryOrganic chemistryCyclopropane Reaction MechanismsCatalytic Alkyne ReactionsCatalytic Cross-Coupling Reactions