A Copper Iodide Cluster-Based Coordination Polymer as an Unconventional Zero-Thermal-Quenching Phosphor
Huixian Miao, Xiancheng Pan, Miao Li, Wenjiang Zhaxi, Jing Wu, Zetao Huang, Luying Liu, Xiao Ma, Shenlong Jiang, Wei Huang, Qun Zhang, Dayu Wu
Abstract
Phosphor-converted white light-emitting diodes (pc-wLEDs) are promising candidates for next-generation solid-state lighting and display technologies. However, most of the conventional phosphors in pc-wLED devices suffer from serious thermal quenching (TQ) at high temperatures. Herein, we investigate an unconventional high-efficiency metal–halide cluster-based phosphor with dynamic Cu–Cu interactions that can resist the TQ effect of photoluminescence. The temperature-dependent structure and solid-state and in situ NMR spectroscopy reveal that the weakening of the Cu–Cu interaction in such a phosphor system enables the electronic structural transition from a bonding to a nonbonding state and hence sustains the PL efficiency at high temperatures (up to 100 °C). The pc-wLEDs incorporating the zero-TQ phosphor show a rapid brightness rise even at a high bias current (1000 mA) with a color rendering index as high as 90, comparable to the commercial phosphor-based prototype LEDs (e.g., YAG:Ce3+). This work establishes a novel prototype of a cluster-based phosphor featuring dynamic intermetallic interactions, which paves the way for the exploration of pc-wLEDs against thermal quenching.