An “Umpolung Relay” Strategy: One-Pot, Twice Polarity Inversion Cascade Synthesis of Diversified [60]Fulleroindoles
Xin-Rui Chen, Ying-meng Li, Xiang Li, Jun Xuan, Hongping Zhou, Yupeng Tian, Fei Li
Abstract
An “umpolung relay” strategy, which includes an one-pot, twice polarity inversion cascade of C60 via carbanion and carbocation polarity reversed relay pathway, has been developed for the synthesis of a diverse range of novel [60]fulleroindole derivatives.
Topics & Concepts
UmpolungChemistryPolarity (international relations)CascadeRelayInversion (geology)CarbocationCarbanionCombinatorial chemistryStereochemistryMedicinal chemistryOrganic chemistryCatalysisNucleophileBiochemistryPhysicsQuantum mechanicsStructural basinPaleontologyPower (physics)ChromatographyCellBiologyFullerene Chemistry and ApplicationsGraphene research and applicationsCarbon Nanotubes in Composites