Topologically Precise and Discrete Bottlebrush Polymers: Synthesis, Characterization, and Structure–Property Relationships
Nduka D. Ogbonna, Michael Dearman, Cheng-Ta Cho, Bhuvnesh Bharti, Andrew J. Peters, Jimmy Lawrence
Abstract
= 1.0). As the system becomes more discrete, packing efficiency increases, distinct three-phase Langmuir-Blodgett isotherms are observed, and its glass transition temperature becomes responsive to side-chain sequence. Overall, this work presents a versatile strategy to access a range of precision bottlebrush polymers and unravels the impact of side-chain topology on their macroscopic properties. Precise control over side chains opens a pathway for tailoring polymer properties without changing their chemical makeup.
Topics & Concepts
Characterization (materials science)Property (philosophy)PolymerMaterials scienceNanotechnologyComposite materialPhilosophyEpistemologyAdvanced Polymer Synthesis and CharacterizationSupramolecular Chemistry and ComplexesPolymer composites and self-healing