Icosahedral <i>m</i> -Carboranes Containing Exopolyhedral B–Se and B–Te Bonds
Harrison A. Mills, Fadi Alsarhan, Ta‐Chung Ong, Milan Gembický, Arnold L. Rheingold, Alexander M. Spokoyny
Abstract
-carboranyltellurolate, can be competent nucleophiles and participate in nucleophilic aromatic substitution reactions. Arene substitution chemistry is shown to be further extended to electron-rich species via palladium-mediated cross-coupling chemistry.
Topics & Concepts
ChemistryIcosahedral symmetryCrystallographyStereochemistryBoron Compounds in ChemistryBoron and Carbon Nanomaterials ResearchRadiopharmaceutical Chemistry and Applications