The Mizoroki–Heck reaction between <i>in situ</i> generated alkenes and aryl halides: cross-coupling route to substituted olefins
Anushka Koranne, S. Turakhia, Vikesh Kumar Jha, Sangeeta Gupta, Rangnath Ravi, Abhijeet Mishra, Anil K. Aggarwal, Chandan Kumar Jha, Neelu Dheer, Abadh Kishor Jha
Abstract
generated alkenes, by following a typical Heck coupling mechanism to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination. These reactions solve the issue of alkenes undergoing polymerization at high temperatures and increase reaction efficiency by reducing the reaction time and purification steps.
Topics & Concepts
ArylHalideChemistryIn situHeck reactionCoupling reactionOrganic chemistryCoupling (piping)Polymer chemistryCatalysisMaterials scienceAlkylMetallurgyCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsCyclopropane Reaction Mechanisms