Solution-processed inorganic δ-phase CsPbI<sub>3</sub> electronic synapses with short- and long-term plasticity in a crossbar array structure
Jun Ge, Zelin Ma, Weilong Chen, Xucheng Cao, Jianfeng Yan, Huaheng Fang, Jieli Qin, Zhiyu Liu, Shusheng Pan
Abstract
Electronic synapses based on memristive devices can potentially open a niche area for neuromorphic computing by replicating the function of biological synapses with high fidelity. Recently, two-terminal memristors based on halide perovskites have demonstrated outstanding memristive properties and a variety of synaptic characteristics, combining with their additional advantages such as a solution-processed fabrication method and low crystalline temperature. However, the concerns over the chemical and phase stability of halide perovskites greatly hinder their practical applications. In this study, by using a simple single-step spin-coating method, we report artificial synapses with superior ambient stability (>90 days under ambient conditions) based on fully inorganic nonperovskite δ-phase CsPbI3 in a cross-bar array architecture. The threshold switching memristive device exhibits a moderate ON/OFF ratio, a relatively low operation voltage (0.3 V) and high endurance (>5 × 105). More importantly, the electronic device can emulate synaptic characteristics such as short-term plasticity, paired-pulse facilitation, and the transition from short-term memory to long-term memory with a high output signal-to-noise ratio (>102). This work represents the first record for artificial synapses based on nonperovskite CsPbI3 and will be a step toward achieving low-cost and high-density practical synapse arrays.