Litcius/Paper detail

Method for Judging the Stability of Asphaltenes in Crude Oil

Ruiying Xiong, Jixiang Guo, Wyclif Kiyingi, Hengshui Feng, Tongcheng Sun, Xiaohui Yang, Qing Li

2020ACS Omega53 citationsDOIOpen Access PDF

Abstract

The colloidal instability index (CII) has been widely used for testing the stability of asphaltenes as a classical method. In this study, five oil samples were tested by the CII method; the results obtained greatly differ from the real field results. In our investigation, we combined the Turbiscan LAB stability analyzer and saturate, aromatic, resin, and asphaltene (SARA) analysis to further investigate the asphaltene stability by heptane titration. The results revealed that there exists a threshold volume ratio before the asphaltenes destabilize. The stability of crude oil is related to the saturation solubility of asphaltenes. By testing the CII value of the crude oil in its current state and the CII value of the dissolved asphaltenes in its saturated state, we were able to propose a new way to judge the oil stability.

Topics & Concepts

AsphalteneHeptaneCrude oilChemistryTitrationChromatographyHildebrand solubility parameterSaturation (graph theory)SolubilityColloidChemical engineeringOrganic chemistryPetroleum engineeringMathematicsGeologyCombinatoricsEngineeringPetroleum Processing and AnalysisHydrocarbon exploration and reservoir analysisEnhanced Oil Recovery Techniques