Diffusion-Coefficient Power Laws and Defect-Driven Glassy Dynamics in Swap Acceleration
Gautham Gopinath, Chun-Shing Lee, Xin-Yuan Gao, Xiao-Dong An, Chor‐Hoi Chan, Cho‐Tung Yip, Hai-Yao Deng, Chi-Hang Lam
Abstract
Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swap model with a fraction ϕ_{s} of swap-initiating particles, which can only swap locally with each other or with regular particles. We focus on the swap-dominating regime. At all temperatures studied, particle diffusion coefficients scale with ϕ_{s} in unexpected power laws with temperature-dependent exponents, consistent with the kinetic picture of glassy dynamics. At small ϕ_{s}, swap initiators, becoming defect particles, induce remarkably typical glassy dynamics of regular particles. This supports defect models of glass.