Litcius/Paper detail

A N-bridged strategy enables hemilabile phosphine–carbonyl palladium and nickel catalysts to mediate ethylene polymerization and copolymerization with polar vinyl monomers

Lei Cui, Zhongbao Jian

2020Polymer Chemistry33 citationsDOI

Abstract

N-Bridged phosphine–carbonyl Pd(<sc>ii</sc>) and Ni(<sc>ii</sc>) catalysts enable the enhancement of molecular weights in ethylene polymerization and copolymerization with polar comonomers.

Topics & Concepts

CopolymerPhosphinePolymer chemistryEthyleneMonomerPalladiumNickelCatalysisPolymerizationChemistryPolarMaterials scienceOrganic chemistryPolymerAstronomyPhysicsOrganometallic Complex Synthesis and CatalysisCatalytic Alkyne ReactionsAsymmetric Hydrogenation and Catalysis
A N-bridged strategy enables hemilabile phosphine–carbonyl palladium and nickel catalysts to mediate ethylene polymerization and copolymerization with polar vinyl monomers | Litcius