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Plant seed extract assisted, eco‐synthesized C‐ZnO nanoparticles: Characterization, chromium(VI) ion adsorption and kinetic studies

Srilatha Rao, A.S. Sowmyashree, Gururaj Kudur Jayaprakash, M. Mahadeva Swamy, K Swamynathan, Deepak Kumar

2022Luminescence20 citationsDOI

Abstract

This report attempts to elucidate the potential of plant seed extract assisted synthesis of graphite-based zinc oxide nanoparticles (C-ZnO NPs) towards removal of chromium(VI) ions from water samples. The graphite-based zinc oxide (C-ZnO) composites were characterized using thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The C-ZnO nanocomposites have found to remove chromium from the sample through an adsorption process. The sensitivity of chromium removal through adsorption is found to be in the range of 40 to 240 mg. The adsorption behaviour was found to be fitting with Langmuir isotherm model and the adsorption reaction follows pseudo second-order kinetics.

Topics & Concepts

AdsorptionThermogravimetric analysisFourier transform infrared spectroscopyChromiumZincScanning electron microscopeLangmuir adsorption modelMaterials scienceNuclear chemistryNanoparticleGraphite oxideGraphiteInorganic chemistryChemical engineeringChemistryNanotechnologyOrganic chemistryMetallurgyComposite materialEngineeringAdsorption and biosorption for pollutant removalNanomaterials for catalytic reactionsMercury impact and mitigation studies